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I/GCSE Chemistry - Metal properties and reactivity

Unit 10 - Metals

· gcse chemistry,metals,metal extraction,reactivity series
  • Metals are important elements that are generally used as good conductors of heat and electricity
  • Reactivity of metals is taught in GCSE Chemistry unit 10
  • Major properties of metals include high melting points, conductors of electricity/heat, high density, malleable, ductile

Reactivity of metals

Metals react with air (oxygen)

  • Metals react with oxygen to produce metal oxides
  • They are oxidation reactions as oxygen is gained
  • General formula: nM(s) + xO2 (g) --> MnOx (s)

Metals react with water/steam

  • Metals more reactive than copper react with water to form metal hydroxide + hydrogen
  • Metals less reactive than (/including)copper DOES NOT REACT with water/steam
  • General formula: nM(s) + xH2O (aq) --> MnOHX (s) + H2 (g)
  • Group I metals react vigorously with cold water
  • e.g. Sodium, Lithium, Potassium, Calcium
  • Group II/Transition metals react with steam
  • e.g. Magnesium, Aluminum, Zinc, Iron, Lead

Metals react with diluted acid

  • Metals react with acid to give out hydrogen gas
  • General formula: M(s) + HCl/HNO3/H2SO4 (aq) --> MX (s) + H2 (g)
  • Observation: bubbling/ colorless gas bubbles forms
  • CAUTION: Group I metals react violently with acid!!

Reactivity series

  • Metals react with other substances to form positive ions(anion)
  • Metals lose their outermost shell electrons to other atoms
  • Meaning that reactivity of a metal = the ease of losing electrons
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Displacement reactions

Definition:

a more reactive metal takes the place of another metal(Positive charged ion) in a compound

  • Examples: Zinc/magnesium/Iron react with acid
  • Metal displaces hydrogen ion
  • Zn (s) + H2SO4 (aq) --> ZnSO4 (aq) + H2 (g)
  • Mg (s) + HCl (aq) --> MgCl (aq) + H2 (g)
  • Reactivity: Mg > Zn > H

Displacement reactions of metal oxides

  • Examples:  Magnesium/lead react with metal solutions
  • Mg (s) + AgNO3 (aq) --> MgNO3 (aq) + Ag (s) (no color change)
  • Pb (s) + CuSO4 (aq) --> PbSO4 (aq) + Cu (s) (pale blue --> colorless)
  • Pay attention to color change in solution
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Extraction of metals

  • Ores are rocks found on earth surface that contain enough metal to make it economical to extract the metal

Physical method:

Panning

  • Metals that are natural occurring on earth/ can be mined directly
  • Gold, Silver, Platinum

Chemical methods:

Direct combustion

  • Less reactive metals that can be extracted by direct burning with oxygen in air
  • Copper, Lead

Carbon reduction

  • Metals less reactive than carbon can be extracted from their oxides by reduction with carbon
  • Usually transition metals like Zinc, Iron, Tin
  • For example, the extraction of copper using carbon reduction
  •  2CuO (s) + C(s) --> 2Cu (s) + CO2 (g)
  • The copper oxide has lost oxygen (reduction)
  • The carbon has gained oxygen (oxidation)

Electrolysis

  • Metals more reactive than carbon
  • Usually group I/II metals: Potassium, Sodium, Magnesium, Calcium, Aluminum
  • For example, the electrolysis of aluminum ores in molten cryolite
  • 2Al2O3 (l) --> 4Al (s) + 3O2 (g)
  • The aluminum ions is reduced
  • The oxygen is oxidized
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Image references:

  • Reactivity series of metals - http://onelearningsolution.blogspot.com/2015/02/33-reactivity-series-of-metals-and-its.html
  • Displacement Reaction - http://www.chemistryland.com/CHM130FieldLab/Lab8/

Drafted by Yoyo (Chemistry)

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