In this I/GCSE Chemistry blog post, we will be looking into how the contact process works, let's go!
The manufacture of sulfuric acid
- First, sulfur dioxide is made, mostly by burning sulfur in air.
- Sulfur trioxide is then made by reacting sulfur dioxide with oxygen.
- The two gases react together in contact with a solid catalyst, vanadium(V) oxide.
- It is a reversible reaction, and so the yield of sulfur trioxide is affected by temperature and pressure.
- Once again, the forward reaction is exothermic, so 450˚C is used as a compromise temperature.
- Despite the fact that a higher pressure would increase yield, a pressure of only 2 atmospheres is used because the yield is already 98% so higher pressures would not be economical.
- The sulfur trioxide is then absorbed into concentrated sulfuric acid to make oleum (H2
S2O7). This is then carefully diluted to make a concentrated solution of sulfuric acid.
Sulfuric acid is used in the manufacture of detergents, fertilisers, and paints.
That is all!
References:
https://www.google.com/url?sa=i&url=http%3A%2F%2Fwww.dynamicscience.com.au%2Ftester%2Fsolutions1%2Fchemistry%2Fsulfuricacid.html&psig=AOvVaw2cV3m97hIhuAuv3FtOQrdH&ust=1629638247874000&source=images&cd=vfe&ved=0CAsQjRxqFwoTCLDK5dmZwvICFQAAAAAdAAAAABAD
https://www.google.com/url?sa=i&url=https%3A%2F%2Fwww.toppr.com%2Fask%2Fcontent%2Fstory%2Famp%2Fsulphuric-acid-preparation-and-physical-properties-53103%2F&psig=AOvVaw2o0o7Exy0wypeXK2PQ8JpR&ust=1629638925290000&source=images&cd=vfe&ved=0CAsQjRxqFwoTCNCRzpycwvICFQAAAAAdAAAAABAI
https://www.google.com/url?sa=i&url=https%3A%2F%2Fpubchem.ncbi.nlm.nih.gov%2Fcompound%2FOleum&psig=AOvVaw3TyoLPglvji91Akmn_zruc&ust=1629639043594000&source=images&cd=vfe&ved=0CAsQjRxqFwoTCNDVs9WcwvICFQAAAAAdAAAAABAD