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CHEM - Esters

Chemistry, organic chemistry, esters - IGCSE | IBDP | DSE | GCE | IAL | AP Chemistry

· chemistry,organic chemistry,esters

Esters

Esters are a group of organic compounds that contain the functional group —COO—. 

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☝️ The structure of esters looks like this ☝️ 

  • R and R' are usually carbon chains.
  • R and R' can be the same carbon chain, or they can also be different.
  • R' cannot be H, since the compound would then become a carboxylic acid instead of an ester.
Examples of esters:
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Formation of Esters

Esters are formed by the reaction between carboxylic acids and alcohols in the presence of an acid catalyst.

carboxylic acid + alcohol → ester + water

For example, the formation of ethyl propanoate from propanoic acid and ethanol looks like:

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Naming of Esters

The names of esters consist of two parts:

— the first part indicates the length of the carbon chain in the alcohol, and the name ends in —yl

— the second part indicates the length of the carbon chain in the carboxylic acid, and the name ends in —oate

For example...

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  1. Ethyl methanoate is formed from ethanol and methanoic acid.
  2. Propyl ethanoate is formed from propanol and ethanoic acid.

Properties of Esters

  • Since esters have very weak attractive forces, they are very volatile.
  • Esters have a very distinctive smell.
These properties of esters make them useful for food flavorings and perfumes.

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