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In this topic of IBDP Biology, we will learn about carbohydrates.
Glucose
- C6H12O6
- Hexose sugar.
- Monomer for starch, glycogen and cellulose.
- Exists normally as a stable ring.
- Carbon 1 combines with oxygen atom on carbon 5.
- Various isomers exist.
- Same molecular formula, different structural formula.
- alpha- glucose
- beta- glucose
- Have opposite arrangement of O and OH on carbon 1.
- This has great significance when forming polysaccharides.

Polysaccharides
- Many sugars.
- Polymers
- Formed by condensation reactions.

- Variable numbers of monosaccharides.
- Branched or unbranched chains.
- May be folded.
- Insoluble due to size.
- Exert no osmotic influence.
- Do not diffuse easily.
- Split into disaccharides and monosaccharides by hydrolysis.
Cellulose
When it comes to IBDP Biology,
- Up to 50% of a cell wall.
- 10,000 β-glucose molecules (approx).
- Joined by β-1,4 glycosidic bonds.
- Long unbranched chains.
- Every other β-glucose is inverted.
- This makes the chains very straight.
- Chains run parallel.
- Hydrogen bonds link the chains together
- They form bundles called microfibrils.
- Groups of microfibrils form cellulose fibres.
- These criss-cross in cell walls.
- They do not stretch in either direction
- This gives it considerable stability.
- It is a valuable structural material.
- Difficult to digest.
- Few organisms possess cellulase.
- Uses – cellophane, paper, cotton.

Starch
- When it comes to IBDP Biology, starch is found in most parts of a plant in starch grains.
- Food reserve from excess glucose:
- Short term in photosynthetic cells
- Food supply in seeds for germination.
- Important food supply in animals.
- Made of α glucose.
- 2 constituent structures:
- Approx 20% of starch.
- α 1,4 glycosidic bonds.
- Spiral structure held together by hydrogen bonds.
- Approx 80& of starch.
- α 1,4 and α 1,6 bonds.
- Branched chains.
- Compact for storage.
- Many branched ends enable rapid hydrolysis to release sugars.
- Amylase digests starch
Glycogen
- When it comes to IBDP Biology, major polysaccharide storage material in animals and fungi.
- Stored mainly in muscles and liver.
- Exists in granules.
- Made of α glucose.
- α 1,6 glycosidic bonds& α 1,4 bonds.
- Similar in structure to amylopectin, though shorter chains -α 1,6 bonds are more frequent.
- Even more compact for storage.
- Rapid hydrolysis due to many enzyme attachment points.

This is the end of this topic
