·
Energy of a Photon
- Photon: a quantum of EM radiation
- E = hf
- E = energy of a photon/J
- h = Plank’s constant (6.63x10-34Js)
- f = frequency/Hz
Electron Volts
- electron volt = the kinetic energy gained by an electron when it is accelerated through a pd of 1V.
- eV = a unit of energy
- 1eV = 1.6x10-19J
- eV = ½ mv2
Experiment measuring Planck's Constant
- Connect an LED of known wavelength in the electrical circuit shown.
- Start off with no current flowing through the circuit, then adjust the variable resistor until a current begins to flow.
- Record the voltage (V0) across the LED & the wavelength of light being emitted.
- Repeat with LEDs of different wavelengths.
- Plot a graph of V0 against 1/λ.
- You should get a straight line with a gradient hc/e. Use this to find h.
Remember this equation, it is very useful in A2/A-level Physics exam!👨🏫
Wave-Particle Duality
- λ = h ÷ mv
- Electron diffraction shows the wave nature of electrons.
- Electrons travelling through polycrystalline graphite will be diffracted by the atoms & spacing between the atoms.
- Diffraction of electrons by matter can be used to determine arrangement of atoms and the size of the nuclei.
Energy Levels in Atoms
- Electrons in atoms exist in discrete energy levels.
- Each level is given a number, n = 1 represents the ground state.
- electrons can move down an energy level by emitting a photon.
- The energy carried by each photon is equal to the difference in energies between two levels.
- ΔE = E2 – E1 = hf = hc/λ.
Hot gases produce line emission spectra
- As you heat gas, many of its electrons move to higher energy levels, and when they fall back to ground state, these electrons emit energy as photons.
- If you split the light from a hot gas with a prism, you get a spectrum.
- Each line on the spectrum corresponds with a particular wavelength.
- Since only certain photon energies are allowed, you only see the corresponding wavelength.
Spectrum
Reference:
https://getrevising.co.uk/resources/quantum_physics
This is the end of the topic!
Drafted by Cherry (Chemistry)