July 5, 2021
- Metals are important elements that are generally used as good conductors of heat and electricity
- Reactivity of metals is taught in GCSE Chemistry unit 10
- Major properties of metals include high melting points, conductors of electricity/heat, high density, malleable, ductile
Reactivity of metals
Metals react with air (oxygen)
- Metals react with oxygen to produce metal oxides
- They are oxidation reactions as oxygen is gained
- General formula: nM(s) + xO2 (g) --> MnOx (s)
Metals react with water/steam
- Metals more reactive than copper react with water to form metal hydroxide + hydrogen
- Metals less reactive than (/including)copper DOES NOT REACT with water/steam
- General formula: nM(s) + xH2O (aq) --> MnOHX (s) + H2 (g)
- Group I metals react vigorously with cold water
- e.g. Sodium, Lithium, Potassium, Calcium
- Group II/Transition metals react with steam
- e.g. Magnesium, Aluminum, Zinc, Iron, Lead
Metals react with diluted acid
- Metals react with acid to give out hydrogen gas
- General formula: M(s) + HCl/HNO3/H2SO4 (aq) --> MX (s) + H2 (g)
- Observation: bubbling/ colorless gas bubbles forms
- CAUTION: Group I metals react violently with acid!!
Reactivity series
- Metals react with other substances to form positive ions(anion)
- Metals lose their outermost shell electrons to other atoms
- Meaning that reactivity of a metal = the ease of losing electrons
Displacement reactions
Definition:
a more reactive metal takes the place of another metal(Positive charged ion) in a compound
- Examples: Zinc/magnesium/Iron react with acid
- Metal displaces hydrogen ion
- Zn (s) + H2SO4 (aq) --> ZnSO4 (aq) + H2 (g)
- Mg (s) + HCl (aq) --> MgCl (aq) + H2 (g)
- Reactivity: Mg > Zn > H
Displacement reactions of metal oxides
- Examples: Magnesium/lead react with metal solutions
- Mg (s) + AgNO3 (aq) --> MgNO3 (aq) + Ag (s) (no color change)
- Pb (s) + CuSO4 (aq) --> PbSO4 (aq) + Cu (s) (pale blue --> colorless)
- Pay attention to color change in solution
Extraction of metals
- Ores are rocks found on earth surface that contain enough metal to make it economical to extract the metal
Physical method:
Panning
- Metals that are natural occurring on earth/ can be mined directly
- Gold, Silver, Platinum
Chemical methods:
Direct combustion
- Less reactive metals that can be extracted by direct burning with oxygen in air
- Copper, Lead
Carbon reduction
- Metals less reactive than carbon can be extracted from their oxides by reduction with carbon
- Usually transition metals like Zinc, Iron, Tin
- For example, the extraction of copper using carbon reduction
- 2CuO (s) + C(s) --> 2Cu (s) + CO2 (g)
- The copper oxide has lost oxygen (reduction)
- The carbon has gained oxygen (oxidation)
Electrolysis
- Metals more reactive than carbon
- Usually group I/II metals: Potassium, Sodium, Magnesium, Calcium, Aluminum
- For example, the electrolysis of aluminum ores in molten cryolite
- 2Al2O3 (l) --> 4Al (s) + 3O2 (g)
- The aluminum ions is reduced
- The oxygen is oxidized
Image references:
- Reactivity series of metals - http://onelearningsolution.blogspot.com/2015/02/33-reactivity-series-of-metals-and-its.html
- Displacement Reaction - http://www.chemistryland.com/CHM130FieldLab/Lab8/
Drafted by Yoyo (Chemistry)