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CHEM - The Hydrogen-Oxygen Fuel Cell

Chemistry, Hydrogen-Oxygen Fuel Cells, Electrochemical Cell- DSE | GCE Chemistry

May 5, 2018

Jumping straight into the example👊

I- Understand the principles of hydrogen-oxygen fuel cell

II- Write the half-equation for reaction occurring at each electrode and the overall equation for reaction in a

hydrogen-oxygen fuel cell

III- State the pros and cons of a hydrogen-oxygen fuel cell

Part I- Principle of ​a hydrogen-oxygen fuel cell

Here is a simplified diagram👇

In the cell, three components are separated from each other by two electrodes.

The fuel (hydrogen) is supplied into the negative electrode(anode) while the oxidant(oxygen) is supplied into the positive electrode(cathode).

Further Details:

The electrolyte in the central compartment is hot concentrated potassium hydroxide solution

Part II

Half-equation at the anode

H2(g) + 2OH-(aq) → 2H2O(l) + 2e-

Half-equation at the cathode

O2(g) + 2H2O(l) + 4e- → 40H-

Overall equation

2H2(g) + O2(g) → 2H2O

Part III

Pros👍

  • Do not emit any air pollutants and only water is produced✔️​
  • High energy efficiency of about 70%✔️​
  • Can operate continuously if the flow of O2(g) and H2(g) can be maintained✔️​

Cons👎

  • Materials used to make the electrodes are expensive  💰  💰 
  • Manufacturing of the cells results in the production of toxic by-products 💀​
  • The fuel(hydrogen) needed can only be produced cheaply by fossil fuels
  • Do not work well at low temperatures *if the temperature drops below 0˚C, the cell will freeze
  • Safety concerns as high-pressure tanks are required to store the hydrogen ☠️​

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