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CHEM - Chemical Tests

Chemistry, chemical tests, gases, metals, cations, anions, water - IGCSE | IBDP | DSE | GCE | AP Chemistry

April 14, 2019

Test for Gases

I. Test for Hydrogen

Method: Place lit splint at the open end of a test tube with the gas.

Result: Burns with a 'squeaky pop' noise.

2H2(g) + O2(g) → 2H2O(l)

II. Test for Oxygen

Method: Place lit splint at the open end of a test tube with the gas.

Result: Splint relights.

III. Test for Carbon Dioxide

Method: Bubble gas through limewater (Ca(OH)2).

Result: Limewater turns milky and cloudy.

CO2(g) + Ca(OH)2(aq) → CaCO3(s) + H2O(l)

IV. Test for Ammonia

Method: Put damp red litmus paper into test solution.

Result: Litmus paper turns blue because of OH- ions.

NH3(g) + H2O(l) → NH4+(aq) + OH-(aq)

V. Test for Chlorine

Method: Put damp litmus paper into test solution.

Result: Litmus paper is bleached and turns white.

Flame Test for Metals

Method: Place a sample of metal on a platinum wire and put it in a non-luminous Bunsen flame.

Result: Each metal will show a specific color on a flame.

Test for Cations

I. Test for ammonium (NH4+) ions

Method: Add aqueous sodium hydroxide (NaOH) to the test solution, and use damp red litmus paper.

Result: Ammonium ion reacts with hydroxide ion to form ammonia gas and water. (NH4+(aq) + OH-(aq) → NH3(g) + H2O(l)) The damp red litmus paper turns blue due to the presence of ammonia.

II. Test for Cu2+, Fe2+, Fe3+

Method: Add aqueous sodium hydroxide (NaOH).

Result: Precipitates of different colors form.

Test for Anions

I. Test for Halide Ions

Method: Add a few drops of dilute nitric acid (HNO3) to react with any carbonate ions that may be present. Add silver nitrate (AgNO3) solution.

Result: Precipitates of different colors form.

II. Test for sulfate (SO42-) ions

Method: Add a few drops of dilute hydrochloric acid (HCl) to react with any carbonate ions that may be present, and then add barium chloride (BaCl2) solution.

Result: White precipitate forms.

SO42-(aq) + Ba2+(aq) → BaSO4(s)

III. Test for carbonate (CO32-) ions

Method: Add dilute acid, and bubble the gas formed into limewater.

Result: Carbonate ions react with dilute acid to form CO2 gas (CO32-(aq) + 2H+(aq) →  CO2(g) + H2O(l)). When carbon dioxide gas is bubbled into limewater, the limewater turns milky and cloudy.

Test for Water

Chemical Test for Water

Method: Add water to anhydrous copper(II) sulfate (CuSO4). 

Result: The white powder turns blue.

CuSO4(s) + 5H2O(l) → CuSO4·5H2O(s)

Physical Test for Purity of Water

Method: Boil/freeze water and measure its boiling point/freezing point.

Result: If the water is pure, the boiling point is 100°C, and the freezing point is 0°C. If the water contains impurities, the boiling/freezing point is different.