Return to site

CHEM - Different Forms of Carbon: Graphite vs. Diamond vs. C60 Fullerene

Chemistry, diamond, graphite, fullerene - IGCSE | IBDP | DSE | GCE | IAL | AP Chemistry

May 30, 2019

Carbon can exist in many different forms. Carbon can exist in these forms:

  • graphite
  • diamond
  • C60 fullerene
Different forms of carbon have different structures and properties.

Graphite

Structure and Bonding

  • Graphite forms a giant covalent structure.
  • Each carbon atom is covalently bonded to 3 other carbon atoms.
  • Carbons form layers of hexagonal rings.
  • The layers are joined by weak intermolecular forces.
  • Since only 3 outer electrons are used to form covalent bonds, 1 electron from each carbon atom becomes delocalised.
Properties
  • Slippery
    • The layers are held by weak intermolecular forces, so layers can easily slide over each other.
  • High melting and boiling point
    • Graphite forms a giant covalent structure with many strong covalent bonds. A lot of thermal energy is needed to break the bonds. 
  • Conductor of electricity
    • The delocalised electron can move freely within each layer, so graphite can conduct electricity.
Uses
  • lubricant
  • electrodes for electrolysis

Diamond

Structure

  • Diamond forms a giant covalent structure.
  • Each carbon atom is covalently bonded to 4 other carbon atoms
Properties
  • Hard
    • Since diamond is a rigid structure held by strong covalent bonds, it is one of the world's hardest materials.
  • High melting and boiling point
    • Diamond forms a giant covalent structure with many strong covalent bonds. A lot of thermal energy is needed to break the bonds. 
  • Does not conduct electricity
    • All 4 outer shell electrons of carbon are used to form covalent bonds, so there is no delocalised electron to conduct electricity.
Uses
  • cutting tool
  • jewelry

C60 Fullerene

Structure and Bonding

  • C60 fullerene has a molecular structure formed by 60 carbon atoms. (It is not a giant covalent structure!!)
  • The shape of the molecule is spherical.
  • Each carbon atom is covalently bonded to 3 other carbon atoms.
  • Since only 3 outer electrons are used to form covalent bonds, 1 electron from each carbon atom becomes delocalised.
  • There are weak intermolecular forces between each fullerene molecule.

Properties

  • Soft and slippery
    • The weak intermolecular forces between fullerene molecules are broken down easily, so fullerene is soft and slippery.
  • Low melting and boiling point
    • Only a small amount of heat energy is needed to overcome to weak intermolecular forces between molecules.
  • Conductor of electricity
    • The delocalised electron is mobile, so fullerene can conduct electricity.
Uses
  • Drug delivery system in the body
  • Lubricant