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AS/A-level Chemistry: Metallic bonding

Metallic bonding

November 29, 2021

What is metallic bond in AS/A-level Chemistry?

  • The forces of attraction between the central core of ions and the sea of delocalized electrons
  • In a metallic lattice, outer shell electrons will repel each other.
  • The repulsive forces between the outer shell electrons, in this structure are so great that the outer shell electrons become delocalized.
  • DELOCALISED ELECTRONS- Not under the control of one specific nucleus. They are shared by many nuclei in structure- able to move freely
  • LOCALISED ELECTRONS- Under the control of one specific nucleus (an example are inner shells)
    • The MORE electron shells a metal has, the WEAKER the metallic bond
    • The FEWER electron shells a metal has, the STRONGER the metallic bond

Melting point:

The strength of the metallic bond depends on:

  • The more delocalized electrons, the stronger the bond and the higher the melting point
  • The more closely packed the atoms are the stronger the bond is and the higher the melting point
  • The electrons are free to move throughout the structure, but the positive ions remain where they are
  • High temperatures are needed to break metallic bonds and dislodge ions from rigid positions in lattice

Conductivity:

  • Solid and liquid metals conduct heat and electricity
  • The delocalized electrons are free to move in the solid lattice.
  • These electrons can act as charge carriers in the conduction of electricity or as energy conductors in the conduction of heat.

Malleable and Ductile:

  • The delocalized electrons in the 'sea' of electrons in the metallic bond, enable the metal atoms or layers to slide past each other when a stress is applied.

This is the end of the topic!